Bioinorganic CatalysisJan Reedijk Marcel Dekker, 1993 - Počet stran: 482 This resource provides the latest research results in bioinorganic catalysis, and suggests new topics for interdisciplinary studies dealing with metal ions, catalysis and biochemical systems - focusing on the molecular level, and spotlighting the direct environment of the metal ion at the active site. perspective of biochemstry/enzymology, inorganic chemistry, geophysics, organic chemistry and homgeneous and heterogeneous catalysis; examines the structures of the catalytic sites at atomic resolution, the specificity and kinetics of the reactions, and the possible practical uses; covers strategies to design, synthesize and apply analogs of the enzymes, emphasizing redox metals; illustrates how the uses for enzymes and the chemical systems based on them in catalytic processes are continually increasing; and discusses metalloenzymes and synthetic analogs for their active sites simultaneously. |
Obsah
Introduction to Bioinorganic Chemistry | 1 |
Introduction to Homogeneous Catalysis | 11 |
Relationships Between Enzymatic and Heterogeneous Catalysis | 21 |
Autorská práva | |
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acid Acta active active site analogs bacteria binding Biochem Biochemistry bioinorganic Biol Biophys bromination carbon catalyst catalytic cycle catechol Chem chemical chemistry cleavage cluster cm¹ Co-C bond coenzyme cofactor complex compounds coordination copper coupling Cu(I Cu(II cytochrome P-450 dehydrogenase derived dinuclear dioxygen diphenyl disulfide electron transfer enzyme EPR signal EXAFS Fe(II FeMoco Figure formation H₂O heme hemerythrin homolysis hydrogen peroxide hydrogenase hydron hydroxylation Inorg intermediate involved iron-sulfur iron-sulfur clusters K. D. Karlin kinetic L. G. Marzilli ligand mechanism metal ions methyl Moco MoFe protein molecule molybdenum molybdopterin monooxygenase nickel Nishide nitrate reductase nitrogen nitrogenase observed oxidative polymerization oxygen atom peroxo phenol polymer polymerization porphyrin presence proposed pterin radical reaction reactivity redox potential reduction role species spectroscopic structure studies substrate subunits suggested sulfite oxidase Tsuchida tyrosinase V-BrPO vanadium X-ray xanthine oxidase