Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 2. 2. 1999 - Počet stran: 624 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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Výsledky 1-5 z 83
Strana 7
... bound together in a chelating form ; i.e. , two or more ligand donor groups are linked in such a way that all of them can simultaneously bind to the metal , resulting in a very stable species . Substrates and reagents in catalytic ...
... bound together in a chelating form ; i.e. , two or more ligand donor groups are linked in such a way that all of them can simultaneously bind to the metal , resulting in a very stable species . Substrates and reagents in catalytic ...
Strana 14
... RhCl ) . Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts operate . Hence , the latter are usually bound by ligands containing nitrogen , oxygen , and sulfur as the 14 Sheldon.
... RhCl ) . Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts operate . Hence , the latter are usually bound by ligands containing nitrogen , oxygen , and sulfur as the 14 Sheldon.
Strana 34
... bound metal complexes exist at neutral pH to act as effective nucleophiles toward esters and amides . More typically , metals with chelating ligands have been used to prevent precipitation of metal oxides or hydroxides at neutral pH ...
... bound metal complexes exist at neutral pH to act as effective nucleophiles toward esters and amides . More typically , metals with chelating ligands have been used to prevent precipitation of metal oxides or hydroxides at neutral pH ...
Strana 35
... bound to the protein . The organophosphate - degrading enzymes then became of considerable interest in light of their ability to detoxify such lethal compounds . The structure of the active center and elucidation of the hydrolysis ...
... bound to the protein . The organophosphate - degrading enzymes then became of considerable interest in light of their ability to detoxify such lethal compounds . The structure of the active center and elucidation of the hydrolysis ...
Strana 38
... bound water and an intramolecular type of reaction due to the micellar formation . On the basis of the pH ( 6-8.3 ) -insensitive rates , Cu2 + -OH- species 3b ( generated with pK < 6 ) was postulated to be an active catalytic species ...
... bound water and an intramolecular type of reaction due to the micellar formation . On the basis of the pH ( 6-8.3 ) -insensitive rates , Cu2 + -OH- species 3b ( generated with pK < 6 ) was postulated to be an active catalytic species ...
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Běžně se vyskytující výrazy a sousloví
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
Oblíbené pasáže
Strana 14 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
Strana 534 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
Strana 316 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
Strana 202 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
Strana 204 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
Strana 30 - Advanced Zeolite Science and Applications", JC Jansen, M. Stocker, HG Karge and J.
Strana 30 - The Physical Basis for Heterogeneous Catalysis" (E. Drauglis and RI Jaffee, eds.), pp.
Strana 528 - A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi, and A. Finazzi-Agro, J. Mol. Biol., 224, 179-205 (1992).