Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 2. 2. 1999 - Počet stran: 624 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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Strana 13
... involved in catalysis by simple metal salts and their coordination complexes . II . METAL IONS IN BIOLOGICAL CATALYSIS The metal ions of major significance for biological catalysis [ 2 ] are shown in Figure 1. The majority are first ...
... involved in catalysis by simple metal salts and their coordination complexes . II . METAL IONS IN BIOLOGICAL CATALYSIS The metal ions of major significance for biological catalysis [ 2 ] are shown in Figure 1. The majority are first ...
Strana 14
... involved in industrial processes are often triaryl ( alkyl ) phosphane complexes of noble metals ( e.g. , ( PhP ) , RhCl ) . Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts ...
... involved in industrial processes are often triaryl ( alkyl ) phosphane complexes of noble metals ( e.g. , ( PhP ) , RhCl ) . Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts ...
Strana 18
... involved in reactions mediated by metalloporphyrin and metallocorrin complexes ( e.g. , vitamin B - 12 - dependent enzymes ) . V.C. Homolytic Catalysis M + X - Y → M - X + Y ( 4 ) Homolytic catalysis is observed with both ...
... involved in reactions mediated by metalloporphyrin and metallocorrin complexes ( e.g. , vitamin B - 12 - dependent enzymes ) . V.C. Homolytic Catalysis M + X - Y → M - X + Y ( 4 ) Homolytic catalysis is observed with both ...
Strana 21
... C = c , etc. Figure 6 Catalytic cycle of oxygen transfer catalyzed by CIPO ( Source : Adapted from Ref . 13 ) . the fundamental processes involved in homogeneous catalysis by transition metal Introduction to Homogeneous Catalysis 21.
... C = c , etc. Figure 6 Catalytic cycle of oxygen transfer catalyzed by CIPO ( Source : Adapted from Ref . 13 ) . the fundamental processes involved in homogeneous catalysis by transition metal Introduction to Homogeneous Catalysis 21.
Strana 22
Jan Reedijk, Elisabeth Bouwman. the fundamental processes involved in homogeneous catalysis by transition metal complexes provides a solid basis for further elaboration of these insights . For more detailed introductions to homogeneous ...
Jan Reedijk, Elisabeth Bouwman. the fundamental processes involved in homogeneous catalysis by transition metal complexes provides a solid basis for further elaboration of these insights . For more detailed introductions to homogeneous ...
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Běžně se vyskytující výrazy a sousloví
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
Oblíbené pasáže
Strana 14 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
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