Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 2. 2. 1999 - Počet stran: 624 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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Strana 8
... reactions are beginning to be somewhat understood . Reactions of other metal ions are far less understood . An example of a biomedical reaction that is beginning to be understood is the mechanism of action of platinum antitu- mor ...
... reactions are beginning to be somewhat understood . Reactions of other metal ions are far less understood . An example of a biomedical reaction that is beginning to be understood is the mechanism of action of platinum antitu- mor ...
Strana 9
... reaction , or in a relatively simple acid - base reaction . The presence of the metal at the particular site usually results in activation of the substrates by the metal and the surrounding ligands . Examples of enzymes catalyzing each ...
... reaction , or in a relatively simple acid - base reaction . The presence of the metal at the particular site usually results in activation of the substrates by the metal and the surrounding ligands . Examples of enzymes catalyzing each ...
Strana 13
... reaction . Conse- quently , any subsequent reaction takes place in the absence of solvent and may be compared with bimolecular reactions in the gas phase . The specificity and high rates of enzymatic processes are readily understood on ...
... reaction . Conse- quently , any subsequent reaction takes place in the absence of solvent and may be compared with bimolecular reactions in the gas phase . The specificity and high rates of enzymatic processes are readily understood on ...
Strana 25
... REACTION The kinetics of enzyme reactions was first established by Michaelis and Menten , following the earlier work of Henri [ 23 ] . The famous Michaelis - Menten equation for the kinetics of an enzyme reaction with a single substrate ...
... REACTION The kinetics of enzyme reactions was first established by Michaelis and Menten , following the earlier work of Henri [ 23 ] . The famous Michaelis - Menten equation for the kinetics of an enzyme reaction with a single substrate ...
Strana 26
... reaction is zero order in [ S ] , and Vmax achieved . The simplest interpretation of the equation involves saturation of the active sites with the substrate , which makes Km an effective dissociation constant . The smaller the Km , the ...
... reaction is zero order in [ S ] , and Vmax achieved . The simplest interpretation of the equation involves saturation of the active sites with the substrate , which makes Km an effective dissociation constant . The smaller the Km , the ...
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Běžně se vyskytující výrazy a sousloví
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
Oblíbené pasáže
Strana 14 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
Strana 534 - S. Yoshikawa, K. Shinzawa-Itoh, R. Nakashima, R. Yaono, E. Yamashita, N. Inoue, M. Yao, MJ Fei, CP Libeu, T. Mizushima, H. Yamaguchi, T. Tomizaki and T. Tsukihara, Science, 280 (1998) 1723.
Strana 316 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
Strana 202 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
Strana 204 - Comprehensive Organometallic Chemistry, G. Wilkinson, FGA Stone, and EW Abel, eds., Pergamon Press, Oxford, 1982, Vol.
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