Bioinorganic CatalysisJan Reedijk, Elisabeth Bouwman CRC Press, 2. 2. 1999 - Počet stran: 624 "Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more." |
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Výsledky 1-5 z 56
Strana 2
... stability , and the processes that are regulated and catalyzed by the metal species . The research field that studies metal ions and their interactions with ligands is usually called coordination chemistry . Such metal - ligand ...
... stability , and the processes that are regulated and catalyzed by the metal species . The research field that studies metal ions and their interactions with ligands is usually called coordination chemistry . Such metal - ligand ...
Strana 6
... stable or influencing a metal that in turn is used only to transport a certain biologically active ligand . Toxic ligands ( CO , NO , CN , F , H2S ) can bind to metals in the active site of enzymes , thus inhibiting substrate binding ...
... stable or influencing a metal that in turn is used only to transport a certain biologically active ligand . Toxic ligands ( CO , NO , CN , F , H2S ) can bind to metals in the active site of enzymes , thus inhibiting substrate binding ...
Strana 7
... stable species . Substrates and reagents in catalytic reactions can vary from simple species like O2 , H2O , NH3 , H2 , N2 , CO2 , and NO2 to larger molecules such as ethanol , alkenes , and phenols . Many of these substrate molecules ...
... stable species . Substrates and reagents in catalytic reactions can vary from simple species like O2 , H2O , NH3 , H2 , N2 , CO2 , and NO2 to larger molecules such as ethanol , alkenes , and phenols . Many of these substrate molecules ...
Strana 13
... stability of metalloenzymes , at the heart of the matter their reactions involve coordination catalysis by metal ions . Thus , at the molecu- lar level we are dealing with homogeneous catalysis in aqueous media . However , as Dewar has ...
... stability of metalloenzymes , at the heart of the matter their reactions involve coordination catalysis by metal ions . Thus , at the molecu- lar level we are dealing with homogeneous catalysis in aqueous media . However , as Dewar has ...
Strana 14
... Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts operate . Hence , the latter are usually bound by ligands containing nitrogen , oxygen , and sulfur as the 14 Sheldon.
... Such complexes are not thermodynamically stable under the oxidizing conditions where most biological catalysts operate . Hence , the latter are usually bound by ligands containing nitrogen , oxygen , and sulfur as the 14 Sheldon.
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Běžně se vyskytující výrazy a sousloví
acid Acta active active site amine analogs axial bacteria binding Biochem Biochemistry bioinorganic Biol biological Biophys bridging bromination carbon catalase catalysis catalytic cycle Chem chemistry cleavage cluster Co-C bond coenzyme cofactor complex compounds coordination copper coupling crystal structure cytochrome P-450 dehydrogenase dihydrogen peroxide dinuclear dioxygen dioxygenases donor electron transfer enzyme EXAFS Fe protein Fe(II FeMoco Figure formation H₂ H₂O heme histidine homolysis hydrogen hydrogenases hydrolysis hydron hydroxylation imidazole Inorg intermediate involved iron iron-sulfur iron(III K.D. Karlin kinetic L.G. Marzilli ligand mechanism metal center metal ions methyl Mn"Mn molecule molybdenum molybdenum and tungsten N₂ nickel nitrogen nitrogenase O₂ observed oxidation oxido oxygen oxygen atom pathway peroxo phenol polymerization porphyrin radical reaction reactivity redox reductase reduction residue role Scheme species spectroscopic studies substrate subunit suggest sulfite sulfur superoxide thiolate tion V-BrPO x-ray xanthine oxidase
Oblíbené pasáže
Strana 14 - Zr Hf V Nb Ta Cr Mo W Mn Tc Re Fe Ru Os Co Rh Ir Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C Si...
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Strana 316 - Y. Dong, H. Fujii, MP Hendrich, RA Leising, G. Pan, CR Randall, EC Wilkinson, Y. Zang, L. Que Jr., BG Fox, K. Kauffmann and E.
Strana 202 - JT Bolin, N. Campobasso, SW Muchmore, TV Morgan, and LE Mortenson in Molybdenum Enzymes, Cofactors and Model Systems (EI Stiefel, D. Coucouvanis, and WE Newton, eds.) of ACS Symposium Series 535, American Chemical Society, Washington, DC, 1993, pp.
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